What you are showing should be on the left side of your screen.
As I said before, you have to choose the correct screen on the top right corner in the drop down. Seems like you have the welcome screen open. The welcome screen does not have questions on it, thus no question.pstpl is available.
Once you picked the template, you need to choose the screen right next to it. Once you choose the question screen, you will also see the question.pstpl.
Help us to help you!
Provide your LS version and where it is installed (own server, uni/employer, SaaS hosting, etc.).
Always provide a LSS file (not LSQ or LSG).
Note: I answer at this forum in my spare time, I'm not a LimeSurvey GmbH employee.