Hi, I have the same issue. I'd like to raise the same quesion if you don't mind.
I tried to export the spss syntax file, but Firefox says File NotFound, Firefox couldn't find the file on https://lime-server/index.php?r=admin/export/sa/exportspss/sid/xxxxxx. And Chrome says ERR_INVALID_RESPONSE, the page I require is temporarily not found or removed permanently. It happens when I try to export spss data file as well.
Since you mentioned your survey was quite large, I enlarged the server's memory limitation and max_post_size. It didn't work out. AND, my survey is quite small with 26 quesions.
The spss exportation will generate a file to be downloaded. So I guess maybe there's something wrong with the tmp directory which the tmp file should be in. Of course there is possibility that the system couldn't generate a spss syntax or data file at all. BTW, my server can export a .lss file all right.
I've checked the SPSSGetQuery and SPSSFieldMap functions, but I don't think they are the cause.
The survey that couldn't be exported was imported into limesurvey using a .lss file from a totally diferent limesurvey system in a different server. The one that couldn't export the file is 2.05+ Build 141210 and the original one that can export is 2.05+ Build 140520, where the .lss file is from.
The servers use Unbuntu 12.04. Apache/2.4.4 (Unix) PHP/5.4.14.Mysql 5.5.31.
I'll be really grateful if someone can help me with this!